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Crystal engineering via C—H⋯F and C—H⋯π interactions in two substituted indoles
Authors:A R Choudhury  K Nagarajan  T N Guru Row
Abstract:The crystal structures of 1‐(4‐fluoro­phenyl)‐2‐phenyl‐4,5,6,7‐tetra­hydro‐1H‐indole, C20H18FN, and 1‐(4‐fluoro­phenyl)‐6,6‐di­methyl‐2‐phenyl‐4,5,6,7‐tetra­hydro‐1H‐indole, C22H22FN, have been determined in order to study the role of `organic fluorine' in crystal engineering. These mol­ecules pack in the crystal structure via different types of molecular motifs utilizing weak C—H?F and C—H?π interactions.
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