Abstract: | In the title compound, C18H15OP·C11H8O2, co‐crystallization of triphenylphosphine oxide with 1‐naphthoic acid yields a supramolecular structure held together by one O—H?O and three C—H?O hydrogen bonds. The O—H?O hydrogen bond O?O = 2.592 (2) Å] has little effect on the O=P bond distance. |