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Bis­[tetrakis­(tri­phenyl­phosphine‐κP)silver(I)] di‐μ‐tri­fluoro­acetato‐κ4O:O′‐bis[bis­(tri­fluoro­acetato‐κO)stannate(IV)]
Authors:Shi‐Yao Yang  Zhao‐Xiong Xie  Seik Weng Ng
Abstract:The crystal structure of the title compound, Ag(C18H15P)4]2Sn2(CH3)4(CF3CO2)6], consists of discrete tetrahedral cations and trans‐C2SnO4 octahedral dianions C—Sn—C = 154.6 (2)°]. The dianion lies about a center of inversion and the two Sn atoms are linked unevenly by the carboxyl­ate unit Sn—O = 2.291 (3) Å and SnO = 2.818 (3) Å].
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