Abstract: | The crystal structure of the title compound, Ag(C18H15P)4]2Sn2(CH3)4(CF3CO2)6], consists of discrete tetrahedral cations and trans‐C2SnO4 octahedral dianions C—Sn—C = 154.6 (2)°]. The dianion lies about a center of inversion and the two Sn atoms are linked unevenly by the carboxylate unit Sn—O = 2.291 (3) Å and SnO = 2.818 (3) Å]. |