Abstract: | The title compound, [Ag2(C2F3O2)2(C5H6N2)2], is a dinuclear AgI complex with inversion symmetry. Each Ag atom is three‐coordinated by two N atoms from two different 2‐aminopyridine ligands and by one O atom from a trifluoroacetate anion, giving an approximately trigonal coordination environment. In the crystal packing, molecules are connected by N—H⋯O and N—H⋯F hydrogen bonds, forming layers parallel to the (001) plane. |