trans‐Dichloro‐cis‐bis(3,6‐dimethylcarbazolyl)‐cis‐bis(tetrahydrofuran)zirconium(IV) benzene sesquisolvate |
| |
Authors: | Cara L. Nygren M. E. T. Bragg John F. C. Turner |
| |
Abstract: | In the title compound, [ZrCl2(C14H12N)2(C4H8O)2]·1.5C6H6, the Zr atom is pseudo‐octahedral, with two Cl atoms in trans positions and two tetrahydrofuran molecules in cis positions. The two 3,6‐dimethylcarbazolyl ligands are in cis positions and are canted with respect to one another. The two Zr—N distances are 2.1148 (18) and 2.1236 (18) Å, and the N—Zr—N angle is 95.08 (7)°. The title compound crystallizes as the benzene solvate, with one of the benzene molecules positioned on an inversion center. |
| |
Keywords: | |
|
|