Bis[(R)‐3,5‐dichloro‐N‐(1‐phenylethyl)salicylideneaminato‐κ2N,O]copper(II) and bis[(R)‐3‐ethoxy‐N‐(1‐phenylethyl)salicylideneaminato‐κ2N,O]copper(II) |
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Authors: | Takashiro Akitsu Yasuaki Einaga |
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Abstract: | The title compounds, Cu(C15H12Cl2NO)2], (I), and Cu(C17H18NO2)2], (II), both adopt a compressed tetrahedral trans‐CuN2O2] coordination geometry, the molecules having an umbrella conformation overall. These complexes differ from one another with respect to the 1‐phenylethylamine moieties, the direction of the benzene rings being either inside in (I)] or inside and outside in (II)] of the molecules. The crystals of (I) and (II) have Δ(R,R) and Λ(R,R) absolute configurations, respectively. |
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