| Abstract: | The structure of Li3+xV6O13 x = 0.24 (3)] at 95 K has been solved and refined using single‐crystal X‐ray diffraction. The refined lithium content corresponds to two fully occupied Li sites and one partially occupied Li site. A doubling of the c axis is observed upon cooling from room temperature, and this change is associated with shifts of the V atoms. The resulting space group is C2/c. The Li disorder present in the Li3V6O13 phase at room temperature is also observed in the low‐temperature phase reported here. |
