[Benzylbis(dimethylamino)methylsilyl‐κ2C,N](N,N,N′,N′‐tetramethylethylenediamine‐κ2N,N)lithium(I) |
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Authors: | He‐Ping Shi Dian‐Sheng Liu Shu‐Ping Huang |
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Abstract: | The title compound, [Li(C12H21NSi)(C6H16N2)], is an intermediate in the synthesis of the corresponding organometallic compounds. The molecule has an unusual C—Si—N—Li four‐membered heterocycle which adopts a folded conformation, with the coordination around the Li, N, C and Si atoms being distorted tetrahedral. Its structure is strongly supported by 1H NMR, 13C NMR and 13C–1H correlation spectra. The compound has potential for application in the synthesis of other novel organometallic compounds. |
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