A novel two‐dimensional cobalt(II) coordination polymer with 1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene |
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Authors: | Bao‐Zong Li Yan‐Fen Peng Yu‐Ping Zhang Bao‐Long Li Yong Zhang |
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Abstract: | In the crystal structure of the title complex, polydiazidocobalt(II)]‐di‐μ‐1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene‐κ4N4:N4′], Co(N3)2(bbtz)2]n, where bbtz is 1,4‐bis(1,2,4‐triazol‐1‐ylmethyl)benzene (C12H12N6), the CoII atom, which lies on an inversion centre, is six‐coordinated by four N atoms from four bbtz ligands and by two N atoms from two azide ligands, in a distorted octahedral coordination environment. The CoII atoms are bridged by four bbtz ligands to form a two‐dimensional 4,4]‐network. |
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