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Diethyl piperazine‐1,4‐diyldioxalate
Authors:Francisco J Martínez‐Martínez  Rodrigo E Rojas‐Prez  Efrn V García‐Bez  Herbert Hpfl  Itzia I Padilla‐Martínez
Abstract:The ethyl oxamate group, N–C(O)–C(O)–OEt, in the title compound, alternatively called diethyl N,N′:N,N′‐bis(ethylene)dioxamate, C12H18N2O6, can be considered as being composed of two singly bonded amide and ester functionalities. The ethyl oxamate group is not planar. The two carbonyl groups are almost perpendicular, with an oxalyl O=C—C=O torsion angle of −111.34 (17)°. The mol­ecule is located on an inversion centre. Infinite supramolecular tapes, propagating along the b axis, are formed through soft C—H⋯O interactions which form a centrosymmetric R(12) motif.
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