4‐Amino‐5‐(2‐hydroxy‐4,4‐dimethyl‐6‐oxocyclohexenylmethyl)‐1‐methyl‐2‐(methylsulfanyl)pyrimidin‐6(1H)‐one: hydrogen‐bonded chains are π‐stacked in pairs |
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Authors: | John N Low Justo Cobo Silvia Cruz Jairo Quiroga Christopher Glidewell |
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Abstract: | Molecules of the title compound, C15H21N3O3S, have a markedly polarized electronic structure; the carbocyclic ring adopts an envelope conformation and the overall molecular conformation appears to be controlled by two intramolecular hydrogen bonds, one each of the O—H?O and N—H?O types. The molecules are linked into C(6) chains by an intermolecular N—H?O hydrogen bond, and pairs of these hydrogen‐bonded chains are linked by a π–π stacking interaction. |
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