Tris{bis[hydrotris(1‐pyrazolyl)borato‐κ3N2,N2′,N2′′]iron(III)} hexaisothiocyanatoiron(III) |
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| Authors: | Shi Wang Yi‐Zhi Li Jing‐Lin Zuo Cheng‐Hui Li Xiao‐Zeng You |
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| Abstract: | The title compound, Fe(C9H10BN6)2]3Fe(NCS)6] or FeIII(Tp)2]3FeIII(NCS)6] Tp is hydrotris(1‐pyrazolyl)borate], crystallizes in space group ; the asymmetric unit comprises one‐half of an Fe(Tp)2]+ cation, with its Fe atom on a crystallographic inversion centre, and one‐sixth of an Fe(NCS)6]3? anion, on a site of symmetry. The anions and cations are stacked into a three‐dimensional supramolecular aggregate via two distinct types of weak C—H?π interactions. |
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