catena‐Poly[[aqua(2,2′‐bipyridine‐κ2N,N′)manganese(II)]‐μ‐terephthalato‐κ3O,O′:O′′] |
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Authors: | Cheng‐Bing Ma Ming‐Qiang Hu Chun‐Xia Zhang Feng Chen Chang‐Neng Chen Qiu‐Tian Liu |
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Abstract: | The title complex, [Mn(C8H4O4)(C10H8N2)(H2O)]n, takes the form of a zigzag chain, with the terephthalate dianion (tp) acting as a tridentate ligand. The MnII center is surrounded by two tp ligands, one water molecule and one 2,2′‐bipyridine (bipy) ligand and exhibits a severely distorted octahedral coordination environment, with cis angles ranging from 57.31 (8) to 123.97 (11)°. The complete solid‐state structure can be described as a three‐dimensional supramolecular framework stabilized by hydrogen‐bonding interactions involving the coordinated water molecule and the carboxy O atoms of the tp ligands, and by π–π stacking interactions involving the bipy rings and the benzene ring of the tp ligand. |
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