Aquabis(2‐nitrobenzoato‐κO)(1,10‐phenanthroline‐κ2N,N′)zinc(II) |
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Authors: | Kou‐Lin Zhang Jian‐Guo Lin Ya‐Qiong Wang Wen‐Lin Xu Jiu‐Tong Chen |
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Abstract: | The title compound, [Zn(C7H4NO4)2(C12H8N2)(H2O)], has been synthesized. X‐Ray analysis reveals that it is a neutral zinc(II) mononuclear carboxylate complex based on mixed N‐ and O‐donor ligands. The Zn atom is five‐coordinate in a distorted trigonal–bipyramidal coordination environment involving two O atoms of two monodentate 2‐nitrobenzoate molecules, two N atoms of a 1,10‐phenanthroline molecule and one O atom of a water molecule. The axial positions are occupied by a carboxylate O atom from the 2‐nitrobenzoate ligand and an N atom from the 1,10‐phenanthroline ligand [N—Zn—O = 167.66 (9)°]. |
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