2,4,6‐Trimethylbenzamide |
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Authors: | Maria Gdaniec,Teresa Olszewska,Tadeusz Poł oń ski |
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Abstract: | The crystal structure of the title compound, C10H13NO, displays an infinite one‐dimensional network composed of primary amide molecules connected by N—H⋯Ozdbnd;C hydrogen bonds involving the anti NH amide H atoms, thus generating a C(4) motif. This network is additionally stabilized by a weak N—H⋯π interaction between the syn‐oriented amide H atom and the aromatic ring of a neighbouring molecule. The distance between the H atom and the ring centroid is 2.50 Å. The amide group and the aryl moiety are nearly perpendicular, forming an intramolecular dihedral angle of 84.69 (6)°. |
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