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Intramolecular hydrogen‐bond‐directed coordination: trans‐bis(N‐benzoyl‐N′‐propyl­thio­urea‐κS)di­iodo­platinum(II) and trans‐bis(N‐benzoyl‐N′‐propyl­thio­urea‐κS)di­bromo­platinum(II)
Authors:Arjan N Westra  Catharine Esterhuysen  Klaus R Koch
Abstract:In the title compounds, trans‐PtI2(C11H14N2OS)2], (I), and trans‐PtBr2(C11H14N2OS)2], (II), respectively, intramolecular N—H⋯O (propyl­amine side) hydrogen bonds in the potentially bidentate thio­urea ligands lock the carbonyl O atoms into six‐membered rings, determining the S‐mono­dentate mode of coordination of these ligands. Intramolecular N—H⋯X (X is I or Br) interactions (benzoyl­amine side) lead to slight distortions of the PtII coordination spheres from ideal square‐planar geometry. The PtII ion is located on an inversion centre in both structures.
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