Rheological Properties and Microstructures of Hydroxyethyl Cellulose/Poly(Acrylic Acid) Blend Hydrogels |
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Authors: | Qiujin Li Jixian Gong Jianfei Zhang |
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Affiliation: | 1. School of Textiles, Tianjin Polytechnic University, Tianjin, China;2. Key Laboratory of Advanced Textile Composites, Tianjin Polytechnic University, Tianjin, China |
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Abstract: | A simple in-situ method was introduced to prepare hydroxyethyl cellulose/poly(acrylic acid) (HEC/PAA) blend hydrogels by forming an interpenetrating network (IPN). Storage modulus (G′) and loss modulus (G″) were improved dramatically compared to HEC. To prove that hydrogen bonds and chemical crosslinking played major roles in improving the hydrogel strength and toughening, and to optimize the components of HEC/PAA blend hydrogels, a series of blend hydrogels with different ratios of HEC to PAA were designed and the corresponding Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), rheological tests, and swelling properties were compared. Crosslinked HEC/PAA blend hydrogel (mol/mol = 1:1) showed the best properties appropriate for opening up biomedical applications of the hydrogel. |
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Keywords: | blend hydrogel interpenetrating network hydrogel microstructure polysaccharide rheology viscosity |
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