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Quantitative Determination of the Components in Corn and Tobacco Samples by Using Near-Infrared Spectroscopy and Multiblock Partial Least Squares
Abstract:Multiblock partial least squares (MB-PLS) are applied for determination of corn and tobacco samples by using near-infrared diffuse reflection spectroscopy. In the model, the spectra are separated into several sub-blocks along the wavenumber, and different latent variable number was used for each sub-block. Compared with ordinary PLS, the importance and the contribution of each sub-block can be balanced by super-weights and the usage of different latent variable numbers. Therefore, the prediction obtained by the MB-PLS model is superior to that of the ordinary PLS, especially for the large data sets of tobacco samples with a large number of variables.
Keywords:Chemometrics  Multiblock  Near-infrared (NIR) spectrum  Partial least squares (PLS)  Quantitative analysis
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