Abstract: | Abstract The kinetics of the acid-catalyzed reactions of di-n-butyl -sulfoxide (BuSOBu), di-phenylsulfoxide (PhSOPh), and di-benzyl -sulfoxide (PhCH2SOCH2Ph) with iodide in a medium of HCLO4 has been followed; the reaction orders with respect to sulfoxide and iodide have been determined and a possible mechanism discussed. |