Determination of Arsenic,Cadmium, Cobalt,Chromium, Nickel,and Lead in Cosmetic Face-Powders: Optimization of Extraction and Validation |
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Abstract: | An analytical method for the quantification of toxic metals in face-powders is presented and discussed. Acid digestion with HNO3-H2O2 or HNO3-HCl was performed and compared with total digestion by HF. The digestion with HNO3-H2O2 was the most suitable for these purposes. Analyses were performed by inductively coupled plasma atomic emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS), whose performances were compared by analyzing three different certified reference materials. The analysis of five commercial face-powders revealed the presence of all the considered metals in the range 0.06–8.0 µg/g. To simulate the bioaccessibility of metals in physiological conditions, a digestion with a simulated sweat solution was performed. In this case, the analysis of the same face-powder samples provided results below the limit of quantification, suggesting low bioaccessibility of the considered trace elements. |
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Keywords: | Cosmetics Face-powders Inductively coupled plasma atomic emission spectroscopy Inductively coupled plasma mass spectrometry Toxic elements Trace metals |
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