Tetranuclear cobalt trimethylacetate Co4(μ3-OH)2(μ-OOCBut)6(C4H6N2O)4 containing coordinated 3-methyl-5-pyrazolone |
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Authors: | S. V. Gorbunov T. O. Denisova E. V. Amel’chenkova S. E. Nefedov |
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Affiliation: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia |
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Abstract: | We found that the reaction of the compound obtained by alloying hydrous cobalt(II) acetate and pivalic acid with 3-methyl-5-pyrazolone in refluxing hexane produces the tetranuclear complex Co4(μ3-OH)2(μ-OOCBut)6·(C4H6N2O)4·2HOOCBut (complex 3). The complex has been structurally characterized using single-crystal X-ray diffraction |
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