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Heterocyclic analogs of pleiadiene. 69. Synthesis and oxidative hydroxylation of 1-alkyl-1,3-diazapyrenium salts
Authors:Borovlev  I. V.  Demidov  O. P.  Chernyshev  A. V.  Pozharskii  A. F.
Affiliation:(1) Department of Biology and Chemistry, Stavropol State University, 1a ul. Pushkina, 355009 Stavropol, Russian Federation;(2) Scientific Research Institute of Physical and Organic Chemistry of Rostov State University, 194/2 ul. Stachka, 344090 Rostov-on-Don, Russian Federation;(3) Department of Chemistry, Rostov State University, 7 ul. Zorge, 344090 Rostov-on-Don, Russian Federation
Abstract:1-Alkyl-1,3-diazapyrenium salts were prepared according to two procedures. Oxidative hydroxylation of these salts afforded 1-alkyl-1,3-diazapyren-2-ones. The spectral characteristics of the resulting compounds are discussed.
Keywords:1,3-diazapyrene  quaternization  oxidative hydroxylation  luminescence
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