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烟草花叶病毒介导合成三角形金纳米片
引用本文:张百慧,周全,卞僮,余慧军,樊华,牛忠伟,吴骊珠,佟振合,张铁锐. 烟草花叶病毒介导合成三角形金纳米片[J]. 影像科学与光化学, 2014, 32(2): 157-162. DOI: 10.7517/j.issn.1674-0475.2014.02.157
作者姓名:张百慧  周全  卞僮  余慧军  樊华  牛忠伟  吴骊珠  佟振合  张铁锐
作者单位:1. 中国科学院 理化技术研究所 光化学转换与功能材料重点实验室, 北京 100190;2. 中国科学院 理化技术研究所 工程塑料国家工程研究中心, 北京 100190;3. 中国科学院大学, 北京 100049
基金项目:973计划项目(2014CB239402,2013CB834505)、国家自然科学基金资助项目(51322213,20901081,51172245,91127005)、中国科学院知识创新工程重要方向性项目(KGCX2-EW-311-3)、中国科学院“百人计划”择优支持项目、中组部“青年拔尖人才支持计划”项目资助
摘    要:利用碱处理烟草花叶病毒的生物还原性和辅助结构导向作用,在室温下以水为溶剂直接还原氯金酸制备出三角形金纳米片。采取透射电子显微镜(TEM)、高分辨透射电子显微镜(HRTEM)、选区电子衍射(SAED)和紫外-可见光谱仪(UV-Vis)等对所制备金纳米片的结构和性能进行了表征。结果显示,所制备三角形金纳米片为单晶,三角面为{111}晶面簇,边长在40 ~120 nm之间,厚度约为15 nm。该材料在可见光区有两个等离子共振吸收峰,在感光成像、生物检测和催化等领域具有很好的应用前景。

关 键 词:  三角形纳米片  烟草花叶病毒  生物还原剂  
收稿时间:2013-11-12

Synthesis of Triangular Gold Nanoplates Mediated by Tobacco Mosaic Virus
ZHANG Baihui,ZHOU Quan,BIAN Tong,YU Huijun,FAN Hua,NIU Zhongwei,WU Lizhu,TONG Zhenhe(TUNG Chen-ho),ZHANG Tierui. Synthesis of Triangular Gold Nanoplates Mediated by Tobacco Mosaic Virus[J]. Imaging Science and Photochemistry, 2014, 32(2): 157-162. DOI: 10.7517/j.issn.1674-0475.2014.02.157
Authors:ZHANG Baihui  ZHOU Quan  BIAN Tong  YU Huijun  FAN Hua  NIU Zhongwei  WU Lizhu  TONG Zhenhe(TUNG Chen-ho)  ZHANG Tierui
Affiliation:1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;2. National Engineering Research Center of Engineering Plastics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;3. University of Chinese Academy of Sciences, Beijing 100049, P.R. China
Abstract:Triangular gold nanoplates were successfully prepared through a room-temperature aquatic biosythetic route mediated by tobacco mosaic virus. The viruses treated with alkali were used as reducing agent and co-structure-directing agent. The structure and optical properties of gold nanoplates were characterized by high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and ultraviolet-visible spectroscope. The as-prepared triangular gold nanoplates are (111)-oriented single crystals. The edge length of the triangular gold nanoplates ranges from 40 to 120 nm and the thickness is about 15 nm. The gold nanoplates have two typical surface plasmonic resonance absorption peaks in the visible light region, which endows them with promising applications in the field of imaging, biosensing and catalysis.
Keywords:gold  triangular nanoplates  tobacco mosaic virus  bioreduction  
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