Model of a nanoparticle in the theory of inhomogeneous medium |
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Authors: | S Sh Rekhviashvili E V Kishtikova and B A Rozenberg |
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Institution: | (1) Center for Biomedical Engineering, Bulgarian Academy of Sciences, Acad. G. Bonchev str. block 105, 1113 Sofia, Bulgaria |
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Abstract: | Basic thermodynamic characteristics (density distribution profile near the surface of a nanoparticle, adsorption, and interfacial
surface tension) of the structureless nanoparticle-vapor/liquid equilibrium system are calculated using a unified approach.
A joint solution of the basic equation in the Van der Waals theory of an inhomogeneous medium for the density distribution
profile in the spherical system of coordinates and the Gibbs equation for the interfacial tension and absorption is obtained.
The features of nucleation of nanoparticles are considered. The results generalize some familiar formulas and provide a more
adequate interpretation of experimental results. |
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Keywords: | |
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