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Synthesis and characterization of axially periodic Zn2SnO4 dendritic nanostructures
Authors:Shen Jun  Ge Bing-Hui  Chu Wei-Guo  Luo Shu-Dong  Zhang Zeng-Xing  Liu Dong-Fang  Liu Li-Feng  Ma Wen-Jun  Ren Yan  Xiang Yan-Juan  Wang Chao-Ying  Wang Gang  Zhou Wei-Ya
Affiliation:Beijing National Laboratory for Condensed MatterPhysics, Institute of Physics, Chinese Academy of Sciences,Beijing 100190, China; Beijing National Laboratory for Condensed MatterPhysics, Institute of Physics, Chinese Academy of Sciences,Beijing 100190, China;Graduate School of the Chinese Academy of Sciences,Beijing 100039, China; National Center for Nanoscience and Nanotechnology,Beijing 100190, China
Abstract:Zn2SnO4 (ZTO) nanowires with a unique dendriticnanostructure were synthesized via a simple one-step thermalevaporation and condensation process. The morphology andmicrostructure of the ZTO nanodendrite have been investigated bymeans of field emission scanning electron microscopy (SEM), x-raydiffraction (XRD) and high-resolution transmission electronmicroscopy (HRTEM). SEM observation revealed the formation ofbranched nanostructures and showed that each branch exhibited aunique periodic structure formed by a row of overlaid rhombohedra ofZTO nanocrystals along the axis of the nanobranch. HRTEM studiesdisplayed that the branches grew homoepitaxially assingle-crystalline nanowires from the ZTO nanowire backbone. Apossible growth model of the branched ZTO nanowires is discussed. Tosuccessfully prepare branched structures would provide an opportunityfor both fundamental research and practical applications, such asthree-dimensional nanoelectronics, and opto-electronic nanodevices.
Keywords:Zn2SnO4   epitaxialgrowth   dendrite   photoluminescence
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