| 含胺基功能性单体的聚合研究——X.N-(N′-次甲基吗啉)取代丙烯酰胺的合成及其聚合 |
| |
| 引用本文： | 张贞浴,周浩然,汪爱蓉,李福绵.含胺基功能性单体的聚合研究——X.N-(N′-次甲基吗啉)取代丙烯酰胺的合成及其聚合[J].高分子学报,1987,0(2):149-152. |
| |
| 作者姓名： | 张贞浴 周浩然 汪爱蓉 李福绵 |
| |
| 作者单位： | 黑龙江大学化学系 哈尔滨
(张贞浴，周浩然，汪爱蓉)，北京大学化学系 北京(李福绵) |
| |
| 摘 要： | <正> 聚丙烯酰胺及其N-取代衍生物是一类医用水凝胶,据Ferruti等报道,含有叔胺基的丙烯酸衍生物的聚合物具有抑制路易斯肺癌扩散的作用,我们曾合成了芳香及脂肪叔胺基取代的丙烯酰胺,并对它们的聚合及其作为氧化还原引发体系组分进行了研究,这些叔胺基取代的丙烯酰胺的聚合物,经复钙法测试,证明具有较好的抗凝血性。
|
| 关 键 词： | 功能性单体 氧化还原引发 表观活化能 N-(N′-次甲基吗啉)甲基丙烯酰胺 |
| 收稿时间： | 1986-01-16 |
STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides |
| |
| ZTANG Zhen-yu,ZHOU Hao-ran,WANG Ai-rong,LI Fu-mian.STUDIES ON THE POLYMERIZATION OF FUNCTIONAL MONOMERS CONTAINING AMINO-GROUP——Ⅹ. Synthesis and Polymerization of Methylene-Morpholino-Group N-Substituted Acrylamides[J].Acta Polymerica Sinica,1987,0(2):149-152. |
| |
| Authors: | ZTANG Zhen-yu ZHOU Hao-ran WANG Ai-rong LI Fu-mian |
| |
| Institution: | Department of Chemistry; Heilongjiang University; Haerbin; Depamment of Chemistry; Peking University; Beijing |
| |
| Abstract: | Methylene-morpholino-group N-substituted acrylamides, i. e. N-(N'-methylene-morpholino) methacrylamide (MMMA) and N-(N'-methylene-morpholino) acrylamide (MMAA) were syn-thsized and polymerized. It was found that these monomers were hardly polymerized initiated with BPO, but could be polymerized with LPO. The polymerization kinetic equations initiated with LPO were obtained asRp= KpMMMP]1.5LPO]0.5Rp = Kp MMAA]1.5LPO]0.5and the overall activation energies were obtained as low as 13.4 Kcal/mol and 9.2 Kcal/mol respectively. The redox nature of the polymerization of these aliphatic tertiary amino-group N-substituted acrylamides initiated with LPO would be suggested. |
| |
| Keywords: | Fuctional Monomer Redox Initiator Orerall Activation Energy N-(N'-methylene-morpholino) methylacrylamide |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高分子学报》浏览原始摘要信息 |
| 点击此处可从《高分子学报》下载免费的PDF全文 |
