Chemistry of enediynyl azides: activation through a novel pathway |
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| Authors: | Basak Amit Roy Sandip K Das Sanket Hazra Amrita B Ghosh Subhash C Jha Shailendra |
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| Affiliation: | Bioorganic Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur, India. absk@chem.iitkgp.ernet.in |
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| Abstract: | The spontaneous activation of a nonaromatic enediynyl azide under ambient conditions has been demonstrated. The aromatic enediyne followed the expected cycloaddition with the alkene in the neighbouring arm to form a stable bridged bicyclic enediyne. |
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