Candoluminescence-a new flame technique for trace analysis-II Determination of nanogram amounts of manganese |
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Authors: | Belcher R Karpel S Townshend A |
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Affiliation: | Chemistry Department, Birmingham University, P.O. Box 363, Birmingham B15 2TT, U.K. |
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Abstract: | The yellow candoluminescence of manganese stimulated in a 8:1 w w calcium oxide-calcium sulphate matrix at the edge of a hydrogen-nitrogen-air flame is used to determine 0.1-3.0 ng of manganese in 1-mul samples. Large amounts of chloride ions enhance the emission, and many transition metals suppress it. |
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