Reductive deacetylation of 3,3,3-trifluoro-1-(2-thenoyl)acetone |
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| Authors: | N. V. Russavskaya V. A. Grabel’nyh E. N. Deryagina N. A. Korchevin |
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| Affiliation: | (1) Irkutsk A. E. Favorsky Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, 664033 |
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| Abstract: | The reaction of 3,3,3-trifluoro-1-(2-thenoyl)acetone with sulfur—hydrazine hydrate—alkali and hydrazine hydrate—alkali systems is effected by reductive fission of the trifluoroacetyl group and leads to the formation of nitrogen-containing derivatives of 2-acetylthiophene. Sodium polysulfide assists the reductive fission of 3,3,3-trifluoro-1-(2-thenoyl)acetone. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 1006–1010, July, 2006. |
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| Keywords: | hydrazine polysulfide anions 3,3,3-trifluoro-1-(2-thenoyl)acetone deacetylation |
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