Unified total syntheses of the inositol polyphosphates: D-I-3,5,6P3, D-I-3,4,5P3, D-I-3,4,6P3, and D-I-3,4,5,6P4 via catalytic enantioselective and site-selective phosphorylation |
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| Authors: | Morgan Adam J Komiya Shio Xu Yingju Miller Scott J |
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| Institution: | Department of Chemistry, Boston College, Chestnut Hill, MA 02467, USA. |
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| Abstract: | Synthetic routes to various inositol polyphosphates have been discovered utilizing catalytic enantioselective and site-selective phosphorylation reactions. The syntheses described herein exploit a common intermediate to gain efficient access to eight unique inositol polyphosphates. |
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