Synthesis and crystal structure of [Mn(NCS)2L2] (L = 3,6-bis-(2-methylpyridyl)-1,2-pyridazine) |
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Authors: | M John Plater Mark R St J Foreman Janet M S Skakle |
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Institution: | (1) Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen, AB24 3UE |
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Abstract: | The synthesis and molecular structure of the title compound are reported. The metal ion has a distorted octahedral geometry and is coordinated by two cis thiocyanate nitrogens, two trans pyridine nitrogens and two cis pyridazine nitrogens. The structure has an orthorhombic space group Pbcn with a = 12.9376(6) Å, b = 13.4312(7) Å, c = 18.8992(9) Å, V = 3284.1(3) Å3, and Z = 8. |
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Keywords: | Manganese thiocyanate pyridazine |
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