The reductive cocondensation of chlorotrimethylsilane and dichlorodimethylsilane |
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| Authors: | O A Petukhova A I Chernyavskii B G Zavin N E Brandukova Ya S Vygodskii |
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| Institution: | (1) D. I. Mendeleev Russian University of Chemical Engeenering, 9 Miusskaya pl., 125190 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
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| Abstract: | Linear and cyclic permethyloligosilanes were prepared by the Wurtz-type cocondensation of chlorotrimethylsilane and dichlorodimethylsilane in the presence of sodium metal or samarium iodide as reducing agents. The yields and composition of the reaction products depend on the cocondensation conditions.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1520–1522, June, 1996. |
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| Keywords: | permethyloligosilanes cocondensation chlorosilanes: sodium metal samarium iodide |
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