多核配合物高自旋基态分子的设计--一个理论和实践的总结

多核配合物高自旋基态分子的设计和合成是分子磁学的一项重要研究内容.作者结合本课题组的工作,总结了合成高自旋基态分子的几种重要模型,包括磁轨道正交、自旋极化、非正规自旋态及自旋失措模型.简要介绍了它们的基本原理和应用这些模型取得成功的一些实例,为分子磁工程的实现提供了一些可行的策略和方法.

Design of Polynuclear Complexes with High Spin Ground State--Summary of Theories and Practices

Design and synthesis of high spin ground state molecules is an important content in the research of molecular magnetism. In order to obtain molecule-based magnets, the first important step is to synthesize molecular entities with a large spin in the ground state. In this paper, we summarized main models allowed to obtain high spin ground state molecules and introduced our work in this field.