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Remarkably mild and efficient catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane using indium(III) chloride |
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| Authors: | Biswanath Das Kongara Damodar Darshanala Saritha Nikhil Chowdhury Martha Krishnaiah |
| Institution: | Organic Chemistry Division-I, Indian Institute of Chemical Technology, Hyderabad 500 007, India |
| Abstract: | The Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane in the presence of a catalytic amount of indium(III) chloride at room temperature produces the corresponding protected homoallylic amines in high yields. |
| Keywords: | Sakurai reaction N-Alkoxycarbonylamino sulfone Allyltrimethylsilane Protected homoallylic amine Indium(III) chloride |
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