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Efficient and rapid experimental procedure for the synthesis of furan diol from d-glucal using ionic liquid
Authors:Marta Teijeira  Yagamare Fall  Francisco Santamarta  Emilia Tojo
Affiliation:Departamento de Química Orgánica, Facultad de Química, Universidad de Vigo, 36200 Vigo, Spain
Abstract:
A new efficient and rapid experimental method and product isolation procedure as well as easy recyclable reaction media is expected to contribute to the development of a green strategy for the synthesis of furan diol from d-glucal. We determine the best conditions of reaction, minimizing the toxicity and finding an environmentally more acceptable process, using [Bmim][MSO4]/InCl3·3H2O as a new solvent system under extremely mild conditions, providing high yields with a dramatic enhancement of reaction rate.
Keywords:Diols   Ionic liquids   Furans   Green-chemistry   Solvent effects
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