| STRUCTURAL RULES OF TRANSITIONMETAL CARBONYL COMPOUNDS |
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| 作者姓名： | 唐敖庆 李前树 |
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| 作者单位： | Institute of Theoretical Chemistry，Jilin University，Changchun，Institute of Theoretical Chemistry，Jilin University，Changchun |
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| 摘 要： | In this article we have proposed two topological rules to account for the electronic structures of transition-metal carbonyl compounds. The second rule is applied to those which have polyhedral metalhc skeletons with triangular faces and their derivates, while the first rule is applied to all the others We have used these two rules to analyze 261 structure-known compounds with the number of metal atoms from 2 to 12, and the results show that the two rules are in good agreement with the experimental facts. Furthermore, we have also derived from the second rule a formula which can be used to account for the electronic structures of closedpacking carbonyl compounds and which is the same as that given by Ciani and his coworkers.
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STRUCTURAL RULES OF TRANSITIONMETAL CARBONYL COMPOUNDS |
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| TANG AOQING AND LI QIANSHU.STRUCTURAL RULES OF TRANSITIONMETAL CARBONYL COMPOUNDS[J].Science in China(Chemistry),1988(8). |
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| Authors: | TANG AOQING AND LI QIANSHU |
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| Abstract: | In this article we have proposed two topological rules to account for the electronic structures of transition-metal carbonyl compounds. The second rule is applied to those which have polyhedral metalhc skeletons with triangular faces and their derivates, while the first rule is applied to all the others We have used these two rules to analyze 261 structure-known compounds with the number of metal atoms from 2 to 12, and the results show that the two rules are in good agreement with the experimental facts. Furthermore, we have also derived from the second rule a formula which can be used to account for the electronic structures of closedpacking carbonyl compounds and which is the same as that given by Ciani and his coworkers. |
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| Keywords: | transition metal carbonyl compounds structure rule electronic eonfiguration EHMO calculations |
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