A theoretical study of the emulsion polymerization of styrene: The effect of the initial dispersion of the system on the polymerization rate and size distribution of polymer-monomer particles |
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| Authors: | M Khaddazh G I Litvinenko I A Gritskova |
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| Institution: | 1. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia
2. Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 105064, Russia
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| Abstract: | A mathematical model of emulsion polymerization that takes into account the possibility of formation of polymer-monomer particles from monomer microdroplets is proposed. It is shown that the theoretically calculated polymerization rate, the concentration of polymer-monomer particles, and their size distribution are governed by the initial state of the original emulsion system (monodisperse or bidisperse system of microdroplets). |
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