Photoluminescent Mn4 single-molecule magnet |
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| Authors: | Beedle Christopher C Stephenson Casey J Heroux Katie J Wernsdorfer Wolfgang Hendrickson David N |
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| Institution: | Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, California 92093-0358, USA. |
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| Abstract: | The synthesis of Mn(4)(anca)(4)(Hmdea)(2)(mdea)(2)].2CHCl(3) (1) is reported along with room temperature fluorescence, UV-vis, and NMR spectra. Direct current magnetization versus field data reveal a S = 8 ground state. Quantized steps in temperature- and field-dependent magnetization versus field hysteresis loops confirm single-molecule magnet behavior. |
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