Synthesis and structure of some cis-and trans-myrtanylstannanes |
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| Authors: | Jens Beckmann Andrew Duthie |
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| Affiliation: | a Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstr. 34-36, 14195 Berlin, Germany
b School of Life and Environmental Sciences, Deakin University, Geelong 3217, Australia |
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| Abstract: | Enantiomerically pure cis- and trans-myrtanylstannanes cis-MyrSnPh3 (1), trans-MyrSnPh3 (2), cis-MyrSnPh2Cl (3), trans-MyrSnPh2Cl (4), cis-MyrSnPhCl2 (5), trans-MyrSnPhCl2 (6), cis-MyrSnCl3 (7), trans-MyrSnCl3 (8) were synthesized and fully characterized by 1H, 13C and 119Sn NMR spectroscopy. The molecular structures of 1, 3, 6, 7, and [trans-MyrSn(OH)Cl2 · H2O]2 (8a) a hydrolysis product of 8, were determined by X-ray crystallography. |
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| Keywords: | Tin Chirality |
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