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Gold(I)-catalyzed [4+2] cycloaddition of N-(hex-5-enynyl) tert-butyloxycarbamates |
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| Authors: | Andrea Buzas Xavier F Le Goff Fabien Gagosz |
| Institution: | a Laboratoire Syntheses Organiques, Ecole Polytechnique, CNRS, Route de Scaclay, F-91128 Palaiseau Cedex, France b Laboratoire Heteroelements et Coordination, Ecole Polytechnique, CNRS, F-91128 Palaiseau Cedex, France |
| Abstract: | A study concerning the gold(I)-catalyzed transformation of N-(hex-5-enynyl) tert-butyloxycarbamates is described. The mild conditions employed allow the moderately efficient but stereoselective synthesis of a range of bicyclic carbamates following a formal 4+2] cycloaddition process. |
| Keywords: | Homogeneous catalysis Gold complexes Cycloaddition Ynamides |
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