Kinetics and mechanism of high-temperature decomposition of di-methyl-di (tert-butyl-peroxy) silane |
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| Authors: | A Ya Gerchikov S R Gizatullina N V Yablokova Yu A Aleksandrov and V S Martemyanov |
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| Institution: | (1) State University, 450074 Ufa, USSR;(2) Department of Chemistry of State University, 603600 Gorky, USSR |
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| Abstract: | Kinetic parameters and rate constants for initiation reaction during thermal decomposition of di-methyl-di (tert-bytylperoxy) silane in tetravalerate-pentaerythrol solution have been determined at temperatures ranging from 170 to 220°C. It has been established that tert-butyl hydroperoxide, the product of homolytic peroxysilane decomposition, takes part in the initiation reaction.
                      -- (- -)  170–220°C.  ,  ,    .
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