Multinuclear complexes containing [Pt2(μ-S)2(Ptolyl3)4] as a metallo-ligand |
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Authors: | Narayan Sanjay Jain Vimal K. |
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Affiliation: | (1) Novel Materials and Structural Chemistry Division, Bhabha Atomic Research Centre, Trombay, Mumbai, 400 085, India |
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Abstract: | Treatment of [PtCl2(Ptolyl3)2] (tolyl = 4-MeC6H4) with Na2S in benzene gave [Pt2(μ2-S)2(Ptolyl3)4] (1), which is soluble in common organic solvents. Reactions of (1) with various metal complexes have been studied and several polynuclear metal aggregates isolated. These new complexes were characterized by elemental analysis and n.m.r. spectroscopy. This revised version was published online in June 2006 with corrections to the Cover Date. |
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