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Flow-injection chemiluminometric analysis of some steroids by their sensitizing effect on the bromate-sulphite reaction
Authors:Aristotelis B. Syropoulos  Evangelos G. Sarantonis  Antony C. Calorkerinos
Affiliation:Laboratory of Analytical Chemistry, University of Athens, Panepistimiopolis, Kouponia, 157 71 Athens Greece
Abstract:The chemiluminescent oxidation of sulphite by bromate was investigated and compared with that by cerium(IV). The reaction is sensitized by various steroid hormones which can thus be determined in the ranges 0.50–20.0μg ml 1 for cortisone; 0.50–5.00 μg ml?1 for hydrocortisone and progesterone and 0.50–6.00 μg ml?1 for testosterone and corticosterone.
Keywords:Steroids  Cortisone  Corticosterone  Hydrocortisone  Progesterone  Testosterone
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