Synergic liquid/liquid extraction of lithium and sodium with 4-acyl-5-pyrazolones with bulky substituents and tri-n-octylphosphine oxide |
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Authors: | Hiroshi Mukai Shoji Miyazaki Shigeo Umetani Sorin Kihara Masakazu Matsui |
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Institution: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611 Japan |
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Abstract: | The synergic liquid/liquid extraction of lithium and sodium with 4-acyl-5-pyrazolones having bulky substituents and tri-n-octylphosphine oxide (TOPO) is described. The maximum percentage extraction and the separation of lithium and sodium were improved by introducing bulky substituents. Quantitative extraction (? 99% ) of lithium could be achieved by adduct formation with TOPO, which enhanced the extraction much more than did triphenylphosphine oxide. The extraction decreased in the solvent order cyclohexane ? benzene ? chloroform, which is the general trend in synergic extractions. |
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