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Indirect fluorescence detection in capillary gas chromatography
Authors:Habib Bagheri  Colin S Creaser
Institution:School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ Great Britain
Abstract:Post-column addition of naphthalene vapour to the effluent from a wide-bore capillary gas chromatographic column, prior to gas-phase fluorescence detection, was used to detect fluorescent and non-fluorescent species as positive and negative peaks, respectively. Quenching constants were determined for nitrobenzene and cyclohexanone using indirect detection.
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