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FOURIER TRANSFORM INFRARED STUDY ON THE HYDRATION OF EXTRACTANT ANIONS——SODIUM SALT OF 2-ETHYLHEXYLPHOSPHONIC ACID MONO-2-ETHYL-HEXYL ESTER-SEC.OCTYL ALCOHOL-WATER SYSTEM
作者姓名:吴瑾光  施鼐  高宏成  陈滇  郭海  翁诗甫  徐光宪
作者单位:Department of Chemistry,Peking University,Department of Chemistry,Peking University,Department of Chemistry,Peking University,Department of Chemistry,Peking University,Department of Chemistry,Peking University,Department of Chemistry,Peking University,Department of Chemistry,Peking University
摘    要:We have observed the effect of hydration on the fourier transform IR spectra of an extrac-tant anion using a subtraction technique. The magnitudes and trends for the observed changesin peak frequencies and intensities of the (P=0), (P--O--C), (P--O--H), H--O--H) and(O--H) bands are reported for the first time, and the reasons for such changes are discussed.

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