Mechanism of disproportionation of 2,2,6,6-tetramethyl-1,4-dioxopiperidinium perchlorate in acidic aqueous medium |
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| Authors: | V A Golubev V D Sen’ |
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| Institution: | 1.Institute of Problems of Chemical Physics,Russian Academy of Sciences,Chernogolovka, Moscow Region,Russian Federation |
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| Abstract: | The cation of 2,2,6,6-tetramethyl-1,4-dioxopiperidinium perchlorate disproportionates in acidic aqueous medium to give piperidinoxyl
and/or 1-hydroxypiperidine, nitrone, and acetone. A mechanism of this reaction was proposed and the rate constants for its
particular steps were calculated. |
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