An evanescent field driven mono-molecular layer photoswitch: coordination and release of metallated macrocycles |
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Authors: | Cook Michael J Nygård Anne-Mette Wang Zhenxin Russell David A |
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Affiliation: | Wolfson Materials and Catalysis Centre, School of Chemical Sciences, University of East Anglia, Norwich, UK NR4 7TJ. m.cook@uea.ac.uk |
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Abstract: | Photoswitching of 'on' and 'off' coordination sites in a self assembled monolayer containing the 4-(arylazo)pyridine chromophore has been achieved using the evanescent field and illustrated through coordination and photon induced release of zinc tetraphenylporphyrin. |
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