Organometallic chemistry of carbaporphyrinoids: synthesis and characterization of nickel(II) and palladium(II) azuliporphyrins |
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| Authors: | Graham Shelley R Ferrence Gregory M Lash Timothy D |
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| Affiliation: | Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA. |
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| Abstract: | Brief treatment of azuliporphyrins 5 with nickel(II) or palladium(II) acetate in refluxing DMF afforded excellent yields of the related chelates; these novel organometallic compounds retain cross-conjugated borderline aromatic structures as judged by UV-Vis and NMR spectroscopy, and X-ray crystallography. |
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