Design and development of cyclohexane-based P,N-ligands for transition metal catalysis |
| |
| Authors: | Caiazzo Aldo Dalili Shadi Yudin Andrei K |
| |
| Institution: | Davenport Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6. |
| |
| Abstract: | reaction: see text] A new class of cyclohexane-based P,N-ligands is readily obtained through aziridine ring opening with suitable phosphorus nucleophiles under acidic conditions. trans-1-Amino-2-diphenylphosphinocyclohexane is resolved with tartaric acid to give the final product in >99% ee. The new ligands show high stability toward oxidation at the phosphorus atom. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
